Flash Point:47 F (8.3 C) (CC)
Autoignition Temp:702 F (372 C)
Lower Limits:1.4%
Upper Limits:14%
Extinguishing Media:regular dry chemical, carbon dioxide, water,
regular foam, alcohol resistant foam Large fires: Use regular foam
or flood with fine water spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. For fires
in cargo or storage area: Cool containers with water from unmanned
hose holder or monitor nozzles until well after fire is out. If
this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let
the fire burn. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
For tank, rail car or tank truck: Evacuation radius: 800 meters
(1/2 mile). Do not attempt to extinguish fire unless flow of
material can be stopped first. Flood with fine water spray. Do not
scatter spilled material with high-pressure water streams. Cool
containers with water spray until well after the fire is out. Apply
water from a protected location or from a safe distance. Avoid
inhalation of material ocombustion by-products. Stay upwind and
keep out of low areas. Water may be ineffective.
Unusual Fire/Explosion Hazard:Severe fire hazard. Vapor/air mixtures
are explosive above flash point. The vapor is heavier than air.
Vapors or gases may ignite at distant ignition sources and flash
back. Containers may rupture or explode if exposed to heat.

Neutralizing Agent:

Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Subject to storage
regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding
required. Protect from physical damage. Store outside or in a
detached building. Store with flammable liquids. Store below 38 C.
Keep separated from incompatible substances.
Other Precautions:

Respiratory Protection: ETHYL ACRYLATE, INHIBITED: ETHYL ACRYLATE: 25
ppm (100 mg/m3) OSHA TWA (skin) 5 ppm (20 mg/m3) OSHA TWA (skin)
(vacated by 58 FR 35338, June 30, 1993) 25 ppm (100 mg/m3) OSHA
STEL (vacated by 58 FR 35338, June 30, 1993) 5 ppm ACGIH TWA 15 ppm
ACGIH STEL 2 ppm recommended TWA (DUPONT) (skin)
Ventilation:Provide local exhaust ventilation system. Ventilation
equipment should be explosion-resistant if explosive concentrations
of material are present. Ensure compliance with applicable exposure
limits.
Protective Gloves:Wear appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles with a faceshield.
Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
ETHYL ACRYLATE, INHIBITED: ETHYL ACRYLATE: 25 ppm (100 mg/m3) OSHA TWA
(skin) 5 ppm (20 mg/m3) OSHA TWA (skin) (vacated by 58 FR 35338,
June 30, 1993) 25 ppm (100 mg/m3) OSHA STEL (vacated by 58 FR
35338, June 30, 1993) 5 ppm ACGIH TWA 15 ppm ACGIH STEL 2 ppm
recommended TWA (DUPONT) (skin)

Boiling Pt:210-212 F (99-100 C)
Melt/Freeze Pt:-98 F (-72 C)
Vapor Pres:29 mmHg @ 20 C
Vapor Density:3.5
Spec Gravity:0.9
pH:Not available
Evaporation Rate & Reference:3.3 (butyl acetate=1)
Solubility in Water:1.5% @ 20 C
Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:clear
COLOR:colorless ODOR:irritating odor
Corrosion Rate:

Stability Indicator/Materials to Avoid:Polymerizes with evolution of
heat. Avoid contact with light or storage and use above room
temperature. Closed containers may rupture violently.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat. Keep out of water supplies and sewers.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of carbon Thermal decomposition products: oxides of carbon
Conditions to Avoid Polymerization:Polymerizes with evolution of heat.
Avoid contact with heat or light and monitor inhibitor content.

Waste Disposal Methods:Dispose in accordance with all applicable
regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262.
Hazardous Waste Number(s): U113.

Toxicological Information:ETHYL ACRYLATE, INHIBITED: IRRITATION DATA:
1204 ppm/14 hour(s)-intermittent eyes-rat; 1204 ppm/15
hour(s)-intermittent eyes-monkey; 500 mg open skin-rabbit mild; 10
mg/24 hour(s) skin-rabbit mild; 45 mg eyes-rabbit mild; 1204 ppm/7
hour(s) eyes-rabbit; 1204 ppm/7 hour(s) eyes-guinea pig TOXICITY
DATA: 1414 ppm/4 hour(s) inhalation-rat LC50; 500 ul/kg skin-rabbit
LD50; 800 mg/kg oral-rat LD50 CARCINOGEN STATUS: IARC: Human No
Adequate Data, Animal Sufficient Evidence, Group 2B; ACGIH: A2
-Suspected Human Carcinogen; EC: Category 2 LOCAL EFFECTS:
Irritant: inhalation, skin, eye Lacrimator: eye ACUTE TOXICITY
LEVEL: Toxic: dermal absorption Moderately Toxic: inhalation,
ingestion TARGET ORGANS: immune system (sensitizer) MEDICAL
CONDITIONS AGGRAVATED BY EXPOSURE: heart or cardiovascular
disorders, respiratory disorders, skin disorders and allergies
TUMORIGENIC DATA: Available. MUTAGENIC DATA: Available.
REPRODUCTIVE EFFECTS DATA: Available. ADDITIONAL DATA: May cross
react with similar compounds.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY DATA: FISH TOXICITY: 2500 ug/L 96 hour(s) LC50
(Mortality) Fathead minnow (Pimephales promelas) INVERTEBRATE
TOXICITY: 12000 ug/L 24 hour(s) LC50 (Mortality) Brine shrimp
(Artemia salina) ENVIRONMENTAL SUMMARY: Toxic to aquatic life.

Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Ethyl acrylate, inhibited ID NUMBER: UN1917 HAZARD CLASS OR
DIVISION: 3 PACKING GROUP: II LABELING REQUIREMENTS: Flammable
liquid

SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: Yes FIRE: Yes
REACTIVE: Yes SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): Ethyl acrylate
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Ethyl acrylate: 1000LBSRQ OSHA PROCESS
SAFETY (29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Known to the
state of California to cause the following: Ethyl acrylate Cancer
(Jul 01, 1989)